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Date: 2-11-2019
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Oxidation and Reduction in Organic Chemistry
We’ve pointed out on several occasions that some of the reactions discussed in this and earlier chapters are either oxidations or reductions. An organic oxidation results in a loss of electron density by carbon, caused either by bond formation between carbon and a more electronegative atom (usually O, N, or a halogen) or by bond-breaking between carbon and a less electronegative atom (usually H). Conversely, an organic reduction results in a gain of electron density by carbon, caused either by bond formationbetween carbon and a less electronegative atom or by bond-breaking between carbon and a more electronegative atom.
Based on these definitions, the chlorination reaction of methane to yield chloromethane is an oxidation because a C - H bond is broken and a C - Cl bond is formed. The conversion of an alkyl chloride to an alkane via aG rignard reagent followed by protonation is a reduction, however, because a C - Cl bond is broken and a C - H bond is formed.
As other examples, the reaction of an alkene with Br2 to yield a 1,2-dibromide is an oxidation because two C - Br bonds are formed, but the reaction of an alkene with HBr to yield an alkyl bromide is neither an oxidation nor a reduction because both a C - H and a C - Br bond are formed.
A list of compounds of increasing oxidation level is shown in Figure 1.1. Alkanes are at the lowest oxidation level because they have the maximum possible number of C - H bonds per carbon, and CO2 is at the highest levelbecause it has the maximum possible number of C - O bonds per carbon. Any reaction that converts a compound from a lower level to a higher level is an oxidation, any reaction that converts a compound from a higher level to a lower level is a reduction, and any reaction that doesn’t change the level is neither an oxidation nor a reduction.
Figure 1.1 Oxidation levels of some common types of compounds.
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مخاطر خفية لمكون شائع في مشروبات الطاقة والمكملات الغذائية
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"آبل" تشغّل نظامها الجديد للذكاء الاصطناعي على أجهزتها
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قسم الشؤون الفكرية يصدر العدد الثاني والعشرين من سلسلة كتاب العميد
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