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Light  
  
2147   02:49 صباحاً   date: 4-11-2020
Author : University of Missouri System
Book or Source : Organic Chemistry ii
Page and Part : .................


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Date: 2-8-2020 740
Date: 7-6-2019 668
Date: 10-6-2019 1289

Light

What we know as light is more properly called electromagnetic radiation. We know from experiments that light acts as a wave. As such, it can be described as having a frequency and a wavelength. The wavelength of light is the distance between corresponding points in two adjacent light cycles, and the frequency of light is the number of cycles of light that pass a given point in one second. Wavelength is typically represented by λ, the lowercase Greek letter lambda, while frequency is represented by ν, the lowercase Greek letter nu (although it looks like a Roman “vee,” it is actually the Greek equivalent of the letter “en”). Wavelength has units of length (meters, centimeters, etc.), while frequency has units of per second, written as s−1 and sometimes called a hertz (Hz). Figure 1.1 “Characteristics of Light Waves” shows how these two characteristics are defined.

Figure 1.1 Characteristics of Light Waves

Light Waves

 

Light acts as a wave and can be described by a wavelength λ and a frequency ν.

One property of waves is that their speed is equal to their wavelength times their frequency. That means we have

speed = λν

For light, however, speed is actually a universal constant when light is traveling through a vacuum (or, to a very good approximation, air). The measured speed of light (c) in a vacuum is 2.9979 × 108 m/s, or about 3.00 × 108 m/s. Thus, we have

c = λν

Because the speed of light is a constant, the wavelength and the frequency of light are related to each other: as one increases, the other decreases and vice versa. We can use this equation to calculate what one property of light has to be when given the other property.

Example 1

What is the frequency of light if its wavelength is 5.55 × 10−7 m?

Solution

We use the equation that relates the wavelength and frequency of light with its speed. We have

3.00×108m/s = (5.55×10-7m)ν

We divide both sides of the equation by 5.55 × 10−7 m and get

ν = 5.41×1014 s-1

Note how the m units cancel, leaving s in the denominator. A unit in a denominator is indicated by a −1 power—s−1—and read as “per second.”

Test Yourself

What is the wavelength of light if its frequency is 1.55 × 1010 s−1?

Answer

0.0194 m, or 19.4 mm

Light also behaves like a package of energy. It turns out that for light, the energy of the “package” of energy is proportional to its frequency. (For most waves, energy is proportional to wave amplitude, or the height of the wave.) The mathematical equation that relates the energy (E) of light to its frequency is

E = hν

where ν is the frequency of the light, and h is a constant called Planck’s constant. Its value is 6.626 × 10−34 J·s — a very small number that is another fundamental constant of our universe, like the speed of light. The units on Planck’s constant may look unusual, but these units are required so that the algebra works out.

Example 2

What is the energy of light if its frequency is 1.55 × 1010 s−1?

Solution

Using the formula for the energy of light, we have

E = (6.626 × 10−34 J·s)(1.55 × 1010 s−1)

Seconds are in the numerator and the denominator, so they cancel, leaving us with joules, the unit of energy. So

E = 1.03 × 10−23 J

This is an extremely small amount of energy—but this is for only one light wave.

Test Yourself

What is the frequency of a light wave if its energy is 4.156 × 10−20 J?

Answer

6.27 × 1013 s−1

Because a light wave behaves like a little particle of energy, light waves have a particle-type name: the photon. It is not uncommon to hear light described as photons.

Wavelengths, frequencies, and energies of light span a wide range; the entire range of possible values for light is called the electromagnetic spectrum. We are mostly familiar with visible light, which is light having a wavelength range between about 400 nm and 700 nm. Light can have much longer and much shorter wavelengths than this, with corresponding variations in frequency and energy. Figure 1.2 “The Electromagnetic Spectrum” shows the entire electromagnetic spectrum and how certain regions of the spectrum are labelled. You may already be familiar with some of these regions; they are all light—with different frequencies, wavelengths, and energies.

Figure 1.2 The Electromagnetic Spectrum

Electromagnetic Spectrum

The electromagnetic spectrum, with its various regions labelled. The borders of each region are approximate.

Exercises

  1. Describe the characteristics of a light wave.

  2. What is a characteristic of a particle of light?

  3. What is the frequency of light if its wavelength is 7.33 × 10−5 m?

  4. What is the frequency of light if its wavelength is 1.226 m?

  5. What is the frequency of light if its wavelength is 733 nm?

  6. What is the frequency of light if its wavelength is 8.528 cm?

  7. What is the wavelength of light if its frequency is 1.19 × 1014 s−1?

  8. What is the wavelength of light if its frequency is 3.66 × 106 s−1?

  9. What is the wavelength of light if its frequency is 1.009 × 106 Hz?

  10. What is the wavelength of light if its frequency is 3.79 × 10−3 Hz?

  11. What is the energy of a photon if its frequency is 5.55 × 1013 s−1?

  12. What is the energy of a photon if its frequency is 2.06 × 1018 s−1?

  13. What is the energy of a photon if its wavelength is 5.88 × 10−4 m?

  14. What is the energy of a photon if its wavelength is 1.888 × 102 m?

Answers

1.

Light has a wavelength and a frequency.

3.

4.09 × 1012 s−15.

4.09 × 1014 s−17.

3.66 × 10−7 m

9.

297 m

11.

3.68 × 10−20 J

13.

3.38 × 10−22 J




هي أحد فروع علم الكيمياء. ويدرس بنية وخواص وتفاعلات المركبات والمواد العضوية، أي المواد التي تحتوي على عناصر الكربون والهيدروجين والاوكسجين والنتروجين واحيانا الكبريت (كل ما يحتويه تركيب جسم الكائن الحي مثلا البروتين يحوي تلك العناصر). وكذلك دراسة البنية تتضمن استخدام المطيافية (مثل رنين مغناطيسي نووي) ومطيافية الكتلة والطرق الفيزيائية والكيميائية الأخرى لتحديد التركيب الكيميائي والصيغة الكيميائية للمركبات العضوية. إلى عناصر أخرى و تشمل:- كيمياء عضوية فلزية و كيمياء عضوية لا فلزية.


إن هذا العلم متشعب و متفرع و له علاقة بعلوم أخرى كثيرة ويعرف بكيمياء الكائنات الحية على اختلاف أنواعها عن طريق دراسة المكونات الخلوية لهذه الكائنات من حيث التراكيب الكيميائية لهذه المكونات ومناطق تواجدها ووظائفها الحيوية فضلا عن دراسة التفاعلات الحيوية المختلفة التي تحدث داخل هذه الخلايا الحية من حيث البناء والتخليق، أو من حيث الهدم وإنتاج الطاقة .


علم يقوم على دراسة خواص وبناء مختلف المواد والجسيمات التي تتكون منها هذه المواد وذلك تبعا لتركيبها وبنائها الكيميائيين وللظروف التي توجد فيها وعلى دراسة التفاعلات الكيميائية والاشكال الأخرى من التأثير المتبادل بين المواد تبعا لتركيبها الكيميائي وبنائها ، وللظروف الفيزيائية التي تحدث فيها هذه التفاعلات. يعود نشوء الكيمياء الفيزيائية إلى منتصف القرن الثامن عشر . فقد أدت المعلومات التي تجمعت حتى تلك الفترة في فرعي الفيزياء والكيمياء إلى فصل الكيمياء الفيزيائية كمادة علمية مستقلة ، كما ساعدت على تطورها فيما بعد .