If you bubble ethane gas (CH3CH3, or EtH) through acids, bases, oxidizing agents, reducing agents—in fact almost any chemical you can think of—it will remain unchanged. Just about the only thing you can do with it is burn it. Yet ethanol (CH3CH2OH, or preferably EtOH— structure in the margin) not only burns, it reacts with acids, bases, and oxidizing agents. The difference between ethanol and ethane is the functional group—the OH, or hydroxyl group. We know that these chemical properties (being able to react with acids, bases, and oxidizing agents) are properties of the hydroxyl group and not just of ethanol because other compounds containing OH groups (in other words, other alcohols) have similar properties, whatever their hydrocarbon frameworks. Your understanding of functional groups will be the key to your understanding of organic chemistry. We shall therefore now go on to meet some of the most important functional groups. We won’t say much about the properties of each group; that will come in Chapter 5

Ethanol The reaction of ethanol with oxidizing agents makes vinegar from wine and sober people from drunk ones. In both cases, the oxidizing agent is oxygen from the air, catalysed by an enzyme in a living system. The oxidation of ethanol by microorganisms that grow in wine left open to the air leads to acetic acid (ethanoic acid) while the oxidation of ethanol by the liver gives acetaldehyde (ethanal).

Human metabolism and oxidation

The human metabolism makes use of the oxidation of alcohols to render harmless other toxic compounds containing the OH group. For example, lactic acid, produced in muscles during intense activity, is oxidized by an enzyme called lactate dehydrogenase to the metabolically useful compound pyruvic acid.

and later. Your task at this stage is to learn to recognize them when they appear in structures, so make sure you learn their names. The classes of compound associated with some functional groups also have names, for example compounds containing the hydroxyl group are known as alcohols. Learn these names too as they are more important than the systematic names of individual compounds. We’ve told you a few snippets of information about each group to help you to get to know something of the group’s character.

مواضيع ذات صلة

Chemical reactions

Rotation and rigidity

The carbonyl group

We can hybridize any atoms

Hybridization of atomic orbitals

Molecular orbitals of molecules with more than two atoms

Other factors affecting degree of orbital interaction

Bonds between different atoms

Forming bonds using 2s and 2p atomic orbitals: σ and π orbitals

Bond order

Why hydrogen is diatomic but helium is not

Breaking bonds